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Back to tab navigation Download options Please wait Back to tab navigation. DR-UV-vis and XPS demonstrate that the oxidation state and the Rh—Rh single bond in the dirhodium node are maintained during the ligand substitution process. Please enable JavaScript to access the full features of the site or access our non-JavaScript page. The individual lamellae of the dirhodium-bdc frameworks are stacked as parallel sheets, which are randomly oriented or slightly ordered.


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Aany Sofia Lilly Thankamony. If the material has been adapted instead of reproduced from the original RSC publication “Reproduced from” can be substituted with “Adapted from”. Catalytically active dirhodium sheet-like coordination polymers are synthesized from their precursors via ligand exchange.

The catalysts show similar catalytic efficiency as the homogeneous catalyst in the model cyclopropanation between ethyl diazoacetate EDA and styrene. Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study. XX is the XXth reference in the list of references.

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Publications – Nachwuchsgruppe Gutmann – Technische Universität Darmstadt

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For reproduction of material from PCCP: In all cases the Ref. The stability and reusability of the catalysts are verified by TG-DTA measurements and leaching tests.

For reproduction of material gutmahn PPS: Residual gutmanj species are investigated by quantitative 19 F MAS NMR which further reflects the configuration of trifluoroacetate in the obtained Rh 2 -bdc Tfand defects in the structure.


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Heterogeneous self-supported dirhodium II catalysts with high catalytic efficiency in cyclopropanation — a structural study J. Authors contributing to RSC publications journal articles, books or book chapters do not need to formally request permission to reproduce material contained in this article provided that the correct acknowledgement is given with the reproduced material.